100390-89-4

Basic information

• Product Name: N-methyl-N-benzoylglycine ethyl ester
• Synonyms: N-methyl-N-benzoylglycine ethyl ester
• CAS NO: 100390-89-4
• Molecular Weight: 221.256
• Mol File: 100390-89-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-methyl-N-benzoylglycine ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-benzoylglycine ethyl ester(100390-89-4)
• EPA Substance Registry System: N-methyl-N-benzoylglycine ethyl ester(100390-89-4)

Safety Data

• Hazardous Substances Data: 100390-89-4(Hazardous Substances Data)

Upstream product

• 13200-60-7 Sarcosine ethyl ester 
• 135364-97-5 tert-butyl benzoyl(tert-butoxycarbonyl)carbamate 
• 1499-53-2 ethyl hippurate 
• 77-78-1 dimethyl sulfate 
• 98-88-4 benzoyl chloride 

Downstream Products

• 693781-60-1 5-cyano-1-methyl-5-phenyl-2,5-dihydro-1H-pyrrole-2,3,4-tricarboxylic acid 2-ethyl ester 3,4-dimethyl ester 
• 102537-12-2 1-Methyl-5-phenyl-1H-pyrrole-2,3,4-tricarboxylic acid 2-ethyl ester 3,4-dimethyl ester 

Relevant articles and documents

Frustrated Lewis Pair Catalyzed Hydrogenation of Amides: Halides as Active Lewis Base in the Metal-Free Hydrogen Activation

A method for the metal-free reduction of carboxylic amides using oxalyl chloride as an activating agent and hydrogen as the final reductant is introduced. The reaction proceeds via the hydrogen splitting by B(2,6-F2-C6H3)3 in combination with chloride as the Lewis base. Density functional theory calculations support the unprecedented role of halides as active Lewis base components in the frustrated Lewis pair mediated hydrogen activation. The reaction displays broad substrate scope for tertiary benzoic acid amides and α-branched carboxamides.

Di-tert-butyl N-Acylimidodicarbonates as Isolable Acylating Agents: Mild Conversion of Primary Carboxamides to Substituted Amides

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