1006035-50-2

Basic information

• Product Name: (-)-N,O-bis(triisopropylsilyl)-D-norvaline
• Synonyms: (-)-N,O-bis(triisopropylsilyl)-D-norvaline
• CAS NO: 1006035-50-2
• Molecular Weight: 429.834
• Mol File: 1006035-50-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (-)-N,O-bis(triisopropylsilyl)-D-norvaline(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-N,O-bis(triisopropylsilyl)-D-norvaline(1006035-50-2)
• EPA Substance Registry System: (-)-N,O-bis(triisopropylsilyl)-D-norvaline(1006035-50-2)

Safety Data

• Hazardous Substances Data: 1006035-50-2(Hazardous Substances Data)

Upstream product

• 2013-12-9 D-norvaline 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Relevant articles and documents

Enantiomerically pure α-amino aldehydes from silylated α-amino acids

(Chemical Equation Presented) The disilylation of α-amino acids 1 to provide 2 (72-87%) was achieved without racemization. An unprecedented borane-mediated semi-reduction strategy was devised to convert 2 to stable, isolable oxazaborolidines 3 (100%) which were hydrolyzed to provide 5 (49-60%) as pure, stable compounds. Analysis of the Mosher amides (8) of the γ-amino esters 7 reveals that ≤2% racemization occurs in the 1 → 8 conversions.