1009-08-1Relevant articles and documents
Preparation and Decarboxylation of Allenyl Acetic Acids: a Route to Substituted Buta-1,3-dienes
Baldwin, Jack E.,Bennett, A. R.,Forrest, Andrew
, p. 250 - 251 (1987)
Propargylic esters undergo the Claisen ester rearrangement to give acetic acids which thermally decarboxylate to give substituted buta-1,3-dienes.
One-pot formation of allylic chlorides from carbonyl derivatives
Fuchter, Matthew J.,Levy, Jean-Noel
supporting information; experimental part, p. 4919 - 4922 (2009/05/31)
(Chemical Equation Presented) An efficient, one-pot method for the conversion of carbonyl electrophiles to allylic chlorides has been developed, by activating magnesium alkoxides in situ using TiCl4.
Incorporation of phenyl-substituted pentadienyl ligands in (pentamethylcyclopentadienyl)ruthenium complexes t
Kulsomphob, Vichien,Turpin, Gregory C.,Kfn-Chung Lam, Chris Youngkin,Trakarnpruk, Wimonrat,Carroii, Pat,Rheingold, Arnold L.,Ernst, Richard D.
, p. 3086 - 3093 (2007/10/03)
The reactions of the [Ru(C5Mej)Cl]4 tetramer with 2, 4-diphenylpenta-l, 3-diene or 3-phenyl- or 1, 5-diphenyIsubstituted pentadienyl anions lead to the incorporation of the expected phenyl-substituted pentadienyl ligands into the respective symmetric Ru(C