101499-01-8

Basic information

• Product Name: Cyclohexanone, 2-[(3,4-dimethoxyphenyl)methyl]-
• Synonyms: 2-Veratryl-cyclohexanon;Cyclohexanone,2-[(3,4-dimethoxyphenyl)methyl];2-(3,4-dimethoxybenzyl)cyclohexanone
• CAS NO: 101499-01-8
• Molecular Formula: C15H20O3
• Molecular Weight: 248.31700
• Mol File: 101499-01-8.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 196-200 °C(Press: 2 Torr)
• Density: 1.083±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Cyclohexanone, 2-[(3,4-dimethoxyphenyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-[(3,4-dimethoxyphenyl)methyl]-(101499-01-8)
• EPA Substance Registry System: Cyclohexanone, 2-[(3,4-dimethoxyphenyl)methyl]-(101499-01-8)

Safety Data

• Hazardous Substances Data: 101499-01-8(Hazardous Substances Data)

Upstream product

• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 53751-40-9 veratryl acetate 

Downstream Products

• 144149-39-3 (E)-3-[7-(3,4-Dimethoxy-benzyl)-2-(4-fluoro-phenyl)-4,5,6,7-tetrahydro-2H-indazol-3-yl]-propenal 
• 144148-16-3 7-(3,4-Dimethoxy-benzyl)-2-(4-fluoro-phenyl)-4,5,6,7-tetrahydro-2H-indazole-3-carbaldehyde 
• 144147-71-7 2-(2,2-Dimethoxy-acetyl)-6-(3,4-dimethoxy-benzyl)-cyclohexanone 

Relevant articles and documents

Trialkylsilyl triflimides as easily tunable organocatalysts for allylation and benzylation of silyl carbon nucleophiles with non-genotoxic reagents

Trialkylsilyl triflimides generated in situ are unique catalysts for the electrophilic benzylation or allylation of trialkylsilylenol ethers or allyl trialkylsilanes with non-genotoxic alkylating reagents such as benzyl and allyl acetates. In most cases the reactions are fast at room temperature and yields are high. The reaction works particularly well with electron-rich benzyl donors including derivatives of pyrrole, indole and furane.