1018967-89-9Relevant articles and documents
Simple reaction conditions for the formation of ketonitrones from ketones and hydroxylamines
Pfeiffer, Jennifer Y.,Beauchemin, Andre M.
supporting information; experimental part, p. 8381 - 8383 (2010/02/17)
(Chemical Equation Presented) The condensation of ketones and hydroxylamines to form ketonitrones was reinvestigated by using thermal conditions previously found to minimize hydroxylamine decomposition (t-BuOH, 110°C). This simple approach allows the formation of exocyclic, acyclic, and α,β-unsaturated ketonitrones with benzylic, linear, and branched nitrogen substituents in modest to excellent isolated yields.