1020734-45-5

Basic information

• Product Name: cis-[(PPh₃)2Pt(9-methyadenine(-H),N₆,N₇)][PF₆]
• Synonyms: cis-[(PPh₃)2Pt(9-methyadenine(-H),N₆,N₇)][PF₆]
• CAS NO: 1020734-45-5
• Molecular Weight: 1012.77
• Mol File: 1020734-45-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-[(PPh₃)2Pt(9-methyadenine(-H),N₆,N₇)][PF₆](CAS DataBase Reference)
• NIST Chemistry Reference: cis-[(PPh₃)2Pt(9-methyadenine(-H),N₆,N₇)][PF₆](1020734-45-5)
• EPA Substance Registry System: cis-[(PPh₃)2Pt(9-methyadenine(-H),N₆,N₇)][PF₆](1020734-45-5)

Safety Data

• Hazardous Substances Data: 1020734-45-5(Hazardous Substances Data)

Upstream product

• 700-00-5 3-methyladenine 
• 60969-19-9 thallium(I) hexafluorophosphate 
• 20555-33-3 bis(triphenylphosphane)carbonatoplatinum(II) dichloromethane monosolvate 

Relevant articles and documents

Synthesis and characterization of cis-[(PPh3)2Pt{9-MeAd(-H),N6N7}]X (X- = NO3, PF6): The first example of a platinum(II) complex containing the N6,N7-chelated 9-methyladenine anion

Reaction between the binuclear hydroxo complex cis-[(PPh3)2Pt(μ-OH)]2X2 (X- = NO3, 1a; PF6-, 1b) and the model DNA base 9-methyladenine (9-MeAd) leads to the formation of the mononuclear species cis-[(PPh3)2Pt{9-MeAd(-H),N6N7}]X (X- = NO3, 2a; PF6, 2b), in which the nucleobase chelates the Pt(II) ion with the N6 and N7 atoms. The coordination mode of the nucleobase has been determinated through a multinuclear (1H, 31P, 13C, 15N and 195Pt) NMR analysis and the nuclearity of the complex has been obtained by E.S.I. mass spectrometry. 2 represents the first example of an isolated platinum complex in which the NH2-deprotonated adenine exhibits this binding mode.