10294-29-8Relevant articles and documents
Durnan, D. D.,Mighell, A. D.,Zapolski, J.,Wood, R. K.
, p. 847 - 850 (1964)
Mathews, J. A.,Watters, L. L.
, p. 108 - 111 (1900)
Rose, T. K.
, p. 881 - 904 (1895)
Dell'Amico, Daniella Belli,Calderazzo, Fausto,Marchetti, Fabio
, (1976)
Morris, H. H.
, p. 917 - 927 (1918)
NOVEL METHOD FOR PRODUCING NON-CYANOGEN GOLD COMPOUND
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Paragraph 0019, (2018/09/12)
PROBLEM TO BE SOLVED: To provide a novel method for producing a useful non-cyanogen gold compound that is available as a gold supply source for electroless and electrolytic plating liquids and contains no cyanogen. SOLUTION: The non-cyanogen gold compound represented by formula (2) can be produced in a good yield by adjusting an aqueous solution of a gold compound represented by formula (1) to a pH of 7.0 to 14.0 and keeping the temperature at 0 to 100°C; adding to the solution a solution dissolving 2-mercaptobenzothiazoles in an aqueous solution of one kind or two or more kinds selected from sodium hydroxide, potassium hydroxide and calcium hydroxide; and reacting them for 1 to 15 minutes. (1) (M is NH4, Na or K; x>0, y>0, a>0, b>0, x+y+a+b-1>1.) (2) (R1 to R4 are H, a halogen atom, -(CH2)nCH3/(n=0 to 6), -O-(CH2)nCH3/(n=0 to 6) or -NO2). SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
NON-CYANIDE GOLD COMPOUND
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Paragraph 0017, (2017/02/28)
PROBLEM TO BE SOLVED: To provide a non-cyanide gold compound having no cyan useful as a gold source for non-electrolytic and electrolytic plating liquid. SOLUTION: There is provided a white powdery crystal of a non-cyanide gold compound by suspending alkali metal salts such as first gold chloride, sodium chloride and potassium chloride and 2-mercaptobenzothiazoles in an aqueous solution, then reacting them under a condition of pH of 7.0 to 13.5 and temperature of 10 to 90°C in a presence of inert gas, column purifying deposited crystal by benzene after a reaction end to coordinate 2-mercaptobenzothiazoles to a gold ion represented by the general formula (1). (1), where R1 to R4 are H, a halogen atom, -CH3, -OCH3 or -NO2. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT