10365-94-3Relevant articles and documents
The synthesis of poly-nitrile aromatic and oligopyridine ligands via palladium-catalyzed cyanation of aryl halides
Veauthier, Jacqueline M.,Carlson, Christin N.,Collis, Gavin E.,Kiplinger, Jaqueline L.,John, Kevin D.
, p. 2683 - 2686 (2005)
Modification of Seller's palladium-catalyzed cyanation procedure for simple aromatic halides leads to a versatile and rapid route to complex multi-nitrile aryl and oligopyridyl ligands that improves on known literature methods. By heating the reagents in the high boiling solvent mesitylene to reflux temperatures at ambient pressure, we have observed the conversion of halogenated precursors to the corresponding nitrile compounds. The resulting compounds can be precipitated from CH2Cl2 solutions of the reaction mixtures and isolated as pure compounds in moderate to high yields. The current approach offers a safer alternative to the pressure tube method, as it does not involve the use of KCN at high pressures. Georg Thieme Verlag Stuttgart.
Synthesis of poly-nitrile aromatics via palladium-catalyzed cyanation of aryl bromides with potassium hexacyanoferrate(II)
Becker, Martin,Schulz, Axel,Voss, Karsten
, p. 1042 - 1051 (2011)
(Chemical Equation Presented) Modification of Beller's palladium-catalyzed cyanation procedure leads to a versatile and rapid route to poly-nitrile aromatics via easily available aryl bromides that improve on known literature methods. All cyanide ions on the iron(II) center of the non-toxic cyanide source [potassium hexacyanoferrate(II)] can be transferred to the aryl halide using palladium(II) acetate and 1,1′-bis(diphenylphosphino)ferrocen (dppf). Copyright Taylor & Francis Group, LLC.
Structural evolution of 2D microporous covalent triazine-based framework toward the study of high-performance supercapacitors
Hao, Long,Ning, Jing,Luo, Bin,Wang, Bin,Zhang, Yunbo,Tang, Zhihong,Yang, Junhe,Thomas, Arne,Zhi, Linjie
, p. 219 - 225 (2015)
A series of nitrogen-containing micropore-donimated materials, porous triazine-based frameworks (PTFs), are constructed through the structural evolution of a 2D microporous covalent triazine-based framework. The PTFs feature predictable and controllable nitrogen doping and pore structures, which serve as a model-like system to more deeply understand the heteroatom effect and micropore effect in ionic liquid-based supercapacitors. The experimental results reveal that the nitrogen doping can enhance the supercapacitor performance mainly through affecting the relative permittivity of the electrode materials. Although microspores' contribution is not as obvious as the doped nitrogen, the great performances of the micropore-dominated PTF suggest that micropore-dominated materials still have great potential in ionic liquid-based supercapacitors.
Corresponding amine nitrile and method of manufacturing thereof
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Paragraph 0132; 0133; 0134; 0136; 0138, (2018/05/24)
The invention relates to a preparation method of nitrile. Compared with the prior art, the preparation method has the characteristics of obvious reduction of the usage amount of ammonia sources, low environmental pressure, low energy consumption, low production cost, high purity and yields of nitrile products, and the like, and can be used for obtaining nitrile with a more complex structure. The invention also relates to a method for preparing corresponding amine with nitrile.
Corresponding amine nitrile and method of manufacturing thereof
-
, (2018/05/24)
The present invention relates to a nitrile manufacturing method, which has characteristics of significantly-reduced ammonia source consumption, low environmental pressure, low energy consumption, low production cost, high nitrile purity, high nitrile yield and the like compared with the method in the prior art, wherein nitrile having a complicated structure can be obtained through the method. The present invention further relates to a method for producing a corresponding amine from the nitrile.