104047-01-0Relevant articles and documents
Iridium-catalyzed coupling reaction of primary alcohols with 1-aryl-1-propynes leading to secondary homoallylic alcohols
Obora, Yasushi,Hatanaka, Shintaro,Ishii, Yasutaka
supporting information; experimental part, p. 3510 - 3513 (2009/12/25)
We report iridium-catalyzed coupling of 2-alkynes such as 1-aryl-1-propynes with primary alcohols leading to secondary homoallylic alcohols as products. This reaction involves an iridium-catalyzed novel catalytic transformation of 2-alkynes and primary al
DIASTEREOSELECTIVITY, DIASTEREOFACIAL SELECTIVITY AND REGIOSELECTIVITY IN THE REACTIONS OF CYNNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM
Coxon, James M.,Eyk, Stephen J. van,Steel, Peter J.
, p. 1029 - 1042 (2007/10/02)
The reaction of cinnamyl chlorie with a series of aryl and alkyl aldehydes mediated by tin and aluminium has been shown to be regioselective and threo diastereoselective.For aldehydes with chirality adjacent to the carbonyl function some diastereofacial s
REDUCTIVE GENERATION OF ACTIVE ZERO-VALENT TIN IN SnCl2-Al SYSTEM AND ITS USE FOR HIGHLY DIASTEREOSELECTIVE REACTION OF CINNAMYL CHLORIDE AND ALDEHYDES.
Uneyama, Kenji,Nanbu, Hiromi,Torii, Sigeru
, p. 2395 - 2396 (2007/10/02)
Highly diastereoselective reaction of cinnamyl chloride with aldehydes was achieved by the use of active zero-valent tin generated in SnCl2-Al system.