104130-08-7

Basic information

• Product Name: 1-(phenylthio)-1-(trimethylsilyl)-4-pentanone
• CAS NO: 104130-08-7
• Molecular Weight: 266.48
• Mol File: 104130-08-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(phenylthio)-1-(trimethylsilyl)-4-pentanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(phenylthio)-1-(trimethylsilyl)-4-pentanone(104130-08-7)
• EPA Substance Registry System: 1-(phenylthio)-1-(trimethylsilyl)-4-pentanone(104130-08-7)

Safety Data

• Hazardous Substances Data: 104130-08-7(Hazardous Substances Data)

Upstream product

• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 78-94-4 methyl vinyl ketone 
• 6704-27-4 (acetylmethyl)mercury chloride 
• 882-33-7 diphenyldisulfane 
• 754-05-2 ethenyltrimethylsilane 

Relevant articles and documents

Three-Component Radical Condensations Involving Benzoylmethyl Radicals, Alkenes, and Diphenyl Disulfide

Acyl-substituted methyl radicals (RCOCH2.; R = H, Me, Ph), generated by photolysis of RCOCH2HgCl, add to alkenes, enol ethers, or vinyl sulfides to give adduct radicals that are readily trapped by PhSSPh to yield a three-component condensation product.The presence of an alkali metal carbonate is crucial in preventing side reactions resulting in the conversion of the mercurial to RCOCH3 by PhSH formed in the photolysis.