10436-82-5

Basic information

• Product Name: Ethanethioic acid, S-(3-methylphenyl) ester
• CAS NO: 10436-82-5
• Molecular Formula: C9H10OS
• Molecular Weight: 166.244
• Mol File: 10436-82-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Ethanethioic acid, S-(3-methylphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanethioic acid, S-(3-methylphenyl) ester(10436-82-5)
• EPA Substance Registry System: Ethanethioic acid, S-(3-methylphenyl) ester(10436-82-5)

Safety Data

• Hazardous Substances Data: 10436-82-5(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 108-40-7 toluene-3-thiol 
• 64-19-7 acetic acid 
• 108-22-5 Isopropenyl acetate 
• 1422-76-0 3-methylbenzenediazonium tetrafluoroborate 
• 10387-40-3 potassium thioacetate 
• 75-36-5 acetyl chloride 

Downstream Products

• 60-35-5 acetamide 
• 35337-64-5 3-methyl-benzenethiol; deprotonated form 

Relevant articles and documents

Methanesulfonic anhydride-promoted sustainable synthesis of thioesters from feedstock acids and thiols

Abstract: An unprecedented metal-, halogen- and solvent-free, MSAA-promoted S-carbonylation of thiols with feedstock acids has been developed. This new transformation provides an efficient and atom-economic strategy for the synthesis of thioesters in a single operation from readily available and inexpensive starting materials. The reaction avoids the use of expensive and hazardous coupling reagents, bases and generates water as the only by-product, thus making this chemical synthetic process more viable, environment-friendly and contributing towards sustainable chemistry. Graphic abstract: [Figure not available: see fulltext.].

Thioesters as Bifunctional Reagents for 2-Naphthylamine Sulfuracylation

An efficient and convenient strategy for the preparation of diaryl sulfides via a Fe-promoted direct sulfuracylation of 2-naphthylamine using thioesters as bifunctional reagents is described. This synthetic strategy features high chemoselectivity, good substrate scope and functional group tolerance. (Figure presented.).

S-Acetylation of Thiols Mediated by Triflic Acid: A Novel Route to Thioesters

This paper demonstrates an efficient, mild, and chemoselective synthesis of various thioesters via a HOTf-catalyzed S-acetylation of aromatic and aliphatic thiols using isopropenyl acetate as a cheap and convenient acetylating agent. During our tests, we also investigated the differences between the activities of metal triflates and triflic acid as catalysts in the acetylation of thiols. Finally, the potential of our concept has been increased by the implementation of Nafion as a heterogeneous catalyst for S-acetylation of thiols.