105500-35-4

Basic information

• Product Name: (1R,2S,6R,7S)-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one
• Synonyms: (1R,2S,6R,7S)-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one
• CAS NO: 105500-35-4
• Molecular Weight: 146.189
• Mol File: 105500-35-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1R,2S,6R,7S)-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,6R,7S)-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one(105500-35-4)
• EPA Substance Registry System: (1R,2S,6R,7S)-tricyclo[5.2.1.0(2,6)]deca-4,8-dien-3-one(105500-35-4)

Safety Data

• Hazardous Substances Data: 105500-35-4(Hazardous Substances Data)

Upstream product

• 1755-01-7 endo-Dicyclopentadien 
• 110793-48-1 exo-5-hydroperoxytricyclo(5.2.1.0.^2,6)deca-3,8-diene 
• 186581-53-3 diazomethane 
• 105469-25-8 1,4,7,7aα-tetrahydro-1-oxo-4α,7α-methano-3aH-indene-(3aR)-3aα-carboxylic acid 

Downstream Products

• 22981-84-6 (3aS^*,4R^*,7S^*,7aR^*)-2,3,4a,4,7,7a-hexahydro-4,7-methano-1H-inden-1-one 
• 542-92-7 cyclopenta-1,3-diene 
• 51493-69-7 sordaricin 
• 188000-48-8 (1R,3aR,4S,7R,7aS)-2,3,3a,4,7,7a-Hexahydro-1H-4,7-methano-inden-1-ol 
• 188000-60-4 (1S,3aS,4R,7S,7aR)-(2,3,3a,4,7,7a-Hexahydro-1H-4,7-methano-inden-1-yl)amine 
• 188000-52-4 (1S,3aR,4S,7R,7aS)-(2,3,3a,4,7,7a-Hexahydro-1H-4,7-methano-inden-1-yl)amine 
• 188000-64-8 (E)-4-((1S,3aS,4R,7S,7aR)-Benzyloxycarbonyl-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-inden-1-yl-amino)-but-2-enoic acid methyl ester 
• 188000-56-8 (E)-4-((1S,3aR,4S,7R,7aS)-Benzyloxycarbonyl-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-inden-1-yl-amino)-but-2-enoic acid methyl ester 
• 72488-04-1 4-(1E-octenyl)-2-cyclopentenon 
• 328583-84-2 (2R,5R)-2-tert-butyl-5-[(1S,2S,3R,6S,7R)-5-oxotricyclo[5.2.1.0^2,6]dec-8-en-3-yl]-5-phenyl-1,3-dioxolan-4-one 
• 62928-74-9 1,3-bishomocubanone 
• 59231-05-9 (+/-)-1-phenyl-(3ac,7ac)-3a,4,7,7a-tetrahydro-4r,7c-methano-inden-1ξ-ol 

Relevant articles and documents

Studies in the synthesis of the thromboxane receptor antagonist EP 092 and its enantiomers

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Regioselective Oxidation of Carbon-Carbon Double Bond of endo-Dicyclopentadiene

endo-9-Oxatetracyclo2.6.08.10>undec-3-ene (2) has been selectively prepared by the oxidation of endo-dicyclopentadiene (1) with chromium trioxide in acetic acid.On the other hand oxidation of 1 by pyridinium chlorochromate furnishes a 1 : 1 mixture of α-chloroketones (3 and 4) in high yield.A plausible mechanism is advanced to explain the formation of 3 and 4.