10574-17-1

Basic information

• Product Name: butan-2-yloxybenzene
• Synonyms: butan-2-yloxybenzene;1-Methylpropoxybenzene;sec-Butyl(phenyl) ether;sec-Butyloxybenzene
• CAS NO: 10574-17-1
• Molecular Formula: C₁₀H₁₄O
• Molecular Weight: 150.22
• Mol File: 10574-17-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 231.78°C (rough estimate)
• Flash Point: 71.6°C
• Appearance: /
• Density: 0.9415
• Vapor Pressure: 0.616mmHg at 25°C
• Refractive Index: 1.4926
• CAS DataBase Reference: butan-2-yloxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: butan-2-yloxybenzene(10574-17-1)
• EPA Substance Registry System: butan-2-yloxybenzene(10574-17-1)

Safety Data

• Hazardous Substances Data: 10574-17-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H14O/c1-3-9(2)11-10-7-5-4-6-8-10/h4-9H,3H2,1-2H3

Upstream product

• 513-48-4 2-butyl iodide 
• 108-95-2 phenol 
• 13784-89-9 di-sec-butyl oxalate 
• 715-11-7 2-tosyloxybutane 
• 139-02-6 sodium phenoxide 
• 107-01-7 butene-2 
• 78-76-2 s-butyl bromide 

Downstream Products

• 14794-55-9 2-(4-sec-Butoxy-phenyl)-N-hydroxy-acetamide 
• 105-46-4 sec-Butyl acetate 
• 99-93-4 4-Hydroxyacetophenone 
• 108-95-2 phenol 
• 89-72-5 2-sec-butylphenol 
• 118-93-4 o-hydroxyacetophenone 
• 99-71-8 4-(1-methylpropyl)phenol 
• 1849-18-9 2,4-di-(sec-butyl)phenol 
• 107-01-7 butene-2 
• 609-46-1 phenol-2-sulfonic acid 
• 3522-86-9 1-(2-methylpropyl)phenol 
• 5892-47-7 2,4,6-tri-(sec-butyl)phenol 
• 103323-60-0 1-bromo-4-(1-methylpropoxy)benzene 
• 15560-75-5 (4-sec-Butoxy-phenyl)-acetic acid ethyl ester 

Relevant articles and documents

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Rearrangement Alkyl Phenyl Ethers to Alkylphenols in the Presence of Cation-exchanged Montmorillonite (Mn+-Mont)

The rearrangement of alkyl phenyl ethers such as 4-phenoxybutan-2-one 1, 1-phenoxybutane 2a, 2-phenoxybutane 2b, 2-methyl-2-phenoxypropane 2c and phenoxycyclohexane 2d have been investigated in the presence of cation-exchanged montmorilonite (Mn+-mont; Mn+ = Zr4+, Al3+, Fe3+ and Zn2+).The ether 1 rearranged to 4-(4-hydroxyphenyl)butan-2-one 3 (raspberry ketone), the odour source of rasprerry, in 16-34percent GLC yield, where Zn2+-mont was the most effective catalyst.Similarly, other ethers 2a-d rearranged to the corresponding alkylphenols in up to 75percent isolated yield with good product selectivity, Al3+-mont being the catalyst of choice.Al3+-Mont was regenerated and resulted in the rearrangement of 2b, 2c and 2d.

FLUORIDE SALTS ON ALUMINA AS REAGENTS FOR ALKYLATION OF PHENOLS AND ALCOHOLS.

THE EFFECTIVENESS OF ALKALI METAL FLUORIDES IMPREGNATED ON ALUMINA AS A REAGENT FOR PROMOTING ALKYLATION WAS OPTIMIZED WITH RESPECT TO THE METAL CATION, THE AMOUNT OF IMPREGNATION, AND THE REACTION SOLVENT. POTASSIUM OR CAESIUM FLUORIDE ONALUMINA IN ACETONITRILE OR 1,2-DIMETHOXYETHANE WAS CONCLUDED TO BE THE BEST REACTION SYSTEM FOR GENERAL USE. O-ALKYLATION OF SUBSTITUTED PHENOLS, PRIMARY AND SECONDARY ALCOHOLS, AND A GLYCOL WAS CARRIED OUT MOSTLY IN GOOD YIELDS UNDER MILDCONDITIONS WITH SIMPLE EXPERIMENTAL PROCEDURES.