1057658-07-7Relevant articles and documents
Fluoride-induced coupling of perfluoroketene dithioacetals with silyl alkynes: A way towards new polyfunctionalized trifluoromethyl building blocks
Nocentini, Tiziano,Brulé, Cédric,Bouillon, Jean-Philippe,Gouault-Bironneau, Sonia,Portella, Charles
, p. 1300 - 1305 (2007)
Under fluoride activation, the vinyl fluorine of perfluoroketene dithioacetal may be substituted by silylated nucleophiles. Using silyl alkynes, a formal transition metal free sila-Sonogashira cross-coupling reaction occurred. The resulting enynes were hy