105827-78-9

Basic information

• Product Name: Admire
• Synonyms: 1-((6-chloro-3-pyridinyl)methyl)-n-nitro-4,5-dihydro-1h-imidazol-2-amine;4,5-dihydro-1-((6-chloro-3-pyridinyl)methyl)-n-nitro-1h-imidazol-2-amin;1-(2-CHLORO-PYRIDINYLMETHYL-5-YL)-2-NITROAMINO-IMIDAZOLINE;1-((6-chloro-3-pyridinyl)methyl)-4,5-dihydro-N-nitro-1H-imidazol-2-amine;Admire(Bayer,Miles);Confidor(Bayer);Gaucho(Bayer;Miles)
• CAS NO: 105827-78-9
• Molecular Formula: C₉H₁₀ClN₅O₂
• Molecular Weight: 255.66
• EINECS: 200-835-2
• Product Categories: Pesticide
• Mol File: 105827-78-9.mol
• Article Data: 28

Chemical Properties

• Melting Point: 136-144°C
• Boiling Point: 442.3 °C at 760 mmHg
• Flash Point: 221.3 °C
• Appearance: /
• Density: 1.59 g/cm³
• Vapor Pressure: 5.47E-07mmHg at 25°C
• Refractive Index: 1.713
• Water Solubility: 0.061 g/100mL at 20℃
• CAS DataBase Reference: Admire(CAS DataBase Reference)
• NIST Chemistry Reference: Admire(105827-78-9)
• EPA Substance Registry System: Admire(105827-78-9)

Safety Data

• Hazard Codes: N:Dangerous for the enviro
• Hazardous Substances Data: 105827-78-9(Hazardous Substances Data)

Usage

Uses

Insecticide.

InChI:InChI=1/C9H10ClN5O2/c10-8-2-1-7(5-12-8)6-13-3-4-14(9(13)11)15(16)17/h1-2,5,11H,3-4,6H2

Upstream product

• 5465-96-3 2-(nitroimino)imidazolidine 
• 70258-18-3 2-chloro-5-(chloromethyl)pyridine 
• 556-88-7 nitroguanidine 
• 107-15-3 ethylenediamine 
• 101990-44-7 N'-((6-chloropyridin-3-yl)methyl)ethane-1,2-diamine 
• 141972-53-4 S,S-dimethyl N-(nitro)imidodithiocarbonate 
• 115970-17-7 Desnitro-imidacloprid 

Downstream Products

• 5326-23-8 6-Chloro-3-pyridinecarboxylic acid 
• 115970-17-7 Desnitro-imidacloprid 
• 120868-66-8 1-[(6-chloro-3-pyridinyl)-methyl]-imidazolidin-2-one 

Relevant articles and documents

Insecticidal and neuroblocking potencies of variants of the imidazoline moiety of imidacloprid-related neonicotinoids and the relationship to partition coefficient and charge density on the pharmacophore

The pharmacophore of the neonicotinoid insecticide imidacloprid, nitroiminoimidazolidine, was modified to heterocycles such as thiazolidine, pyrrolidine, dihydroimidazole, dihydrothiazole, and pyridone conjugated to nitroimine (=NNO2) or nitromethylene (=CHNO2). Their 6-chloro-3-pyridylmethyl or 5-chloro-3-thiazolylmethyl derivatives were examined for insecticidal activity against the American cockroach by injection and for neuroblocking activity using the cockroach ganglion. Most of the compounds having the neonicotinoidal pharmacophore exhibited insecticidal activity at the nanomolar level, which was enhanced in the presence of synergists, and high neuroblocking activity at the micromolar level. Quantitative analysis for the compounds showed that the neuroblocking potency is proportional both to the Mulliken charge on the nitro oxygen atom and to the partition coefficient log P value. The equation for the insecticidal versus neuroblocking potencies indicated that both potencies are related proportionally with each other when the other factors are the same.

Method for synthesizing imidacloprid at high yield

The invention provides a method for synthesizing imidacloprid at a high yield. 2-chloro-5-chloromethylpyridine, ethylenediamine and cyanogen halide, which are used as raw materials, are aminated, cyclized and nitrified to synthesize the imidacloprid. The method has the advantages of high safety in the production process, good purity and high yield of the product, and easiness in industrializationrealization.

Novel nicotinoid structures for covalent modification of wood: An environmentally friendly way for its protection against insects

Timber is constantly exposed to environmental influences under outdoor conditions which limits its lifetime and usability. In order to counteract the damaging processes caused by insects, we have developed a novel and more environmentally friendly method to protect wood materials via covalent modification by organic insecticides. Starting with an important class of synthetic insecticides which are derived from the natural insecticide nicotine, various new carboxylic acid derivatives of imidacloprid were made accessible. These activated neonicotinoids were utilized for the chemical modification of wood hydroxy groups. In contrast to conventional wood preservation methods in which biocides are only physically bound to the surface for a limited time, the covalent fixation of the preservative guarantees a permanent effect against wood pests, demonstrated in standardized biological tests. Additionally, the environmental interaction caused by non-bound neonicotinoids is significantly reduced, since both, a smaller application rate is required and leaching of the active ingredient is prevented. By minimizing the pest infestation, the lifetime of the material increases while preserving the natural appearance of the material.

NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING AMIDE COMPOUND

An object of the present invention is to provide a compound having the controlling activity on a noxious arthropod, and a noxious arthropod controlling agent containing an amide compound of formula (I): wherein X represents a nitrogen atom or a CH group, p represents 0 or 1, A represents a tetrahydrofuranyl group or the like, R1, R2, R3, R4, R5, R6 and R7 represent a hydrogen atom or the like, n represents 1 or 2, Y represents an oxygen atom or the like, m represents any integer of 0 to 7, and Q represents a C1-8 chain hydrocarbon group optionally having a phenyl group or the like, has the excellent noxious arthropod controlling effect.