106657-30-1

Basic information

• Product Name: Acetic acid (R)-phenyl-(R)-tetrahydro-furan-2-yl-methyl ester
• CAS NO: 106657-30-1
• Molecular Weight: 220.268
• Mol File: 106657-30-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Acetic acid (R)-phenyl-(R)-tetrahydro-furan-2-yl-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (R)-phenyl-(R)-tetrahydro-furan-2-yl-methyl ester(106657-30-1)
• EPA Substance Registry System: Acetic acid (R)-phenyl-(R)-tetrahydro-furan-2-yl-methyl ester(106657-30-1)

Safety Data

• Hazardous Substances Data: 106657-30-1(Hazardous Substances Data)

Upstream product

• 13159-16-5 (Z)-5-phenylpent-4-en-1-ol 
• 13159-16-5 (E)-5-phenyl-4-penten-1-ol 
• 64-19-7 acetic acid 
• 144270-76-8 (Z)-5-phenylpent-4-enenitrile 
• 100-52-7 benzaldehyde 
• 17920-83-1 (4Z)-5-phenylpent-4-enoic acid 
• 1445-45-0 Trimethyl orthoacetate 
• 32346-57-9 erythro-1-phenyl-1,2,5-pentanetriol 
• 5331-61-3 gem-diacetate de tetrahydrofurfural 

Relevant articles and documents

Palladium-catalyzed olefin dioxygenation

A general method for the vicinal dioxygenation of olefins was developed using cationic Pd diphosphine complexes as the catalysts and PhI(OAc)2 as the terminal oxidant. In comparison to known Pd-catalyzed vicinal oxidations, this method is suitable for a broad range of olefins in both inter- and intramolecular reactions. An 18O-labeling experiment provides insight into the mechanism of this transformation which presumably involves Pd(II)/Pd(IV) intermediates. Copyright

DIASTEREOSELECTIVITE DANS LA REACTION DES ORGANOMAGNESIENS SUR LE TETRAHYDROFURFURAL ET SON GEM-DIACETATE EN PRESENCE DE HMPT. ACCES AUX DIOLS-1,2 ERYTHRO.

Grignard Reagents - HMPT complexes have been found to be highly stereoselective reagents for the addition to tetrahydrofurfural and for the substitution of an acetoxy group in tetrahydrofurfural gem-diacetate.In both cases, a high erythro/threo ratio was obtained.