106948-30-5Relevant articles and documents
Palladium-Catalysed Desulfitative Heck Reaction Tolerant to Aryl Carbon-Halogen Bonds for Access to (Poly)halo-Substituted Stilbene or Cinnamate Derivatives
Skhiri, Aymen,Salem, Ridha Ben,Soulé, Jean-Francois,Doucet, Henri
, p. 3097 - 3106 (2016/09/09)
The palladium-catalysed desulfitative Heck type reaction of (poly)halo-substituted benzenesulfonyl chlorides with alkenes was investigated. Styrene or acrylates in the presence of bromo- or iodobenzenesulfonyl chlorides and a phosphine-free palladium catalyst were found to afford the expected β-arylated Heck type products with complete regio- and stereoselectivities. The reaction tolerates a variety of substituents on the halobenzenesulfonyl chloride. Moreover, no cleavage of the C-Br and C-I bonds was observed in the course of these reactions, allowing further transformations. Using 4-bromobenzenesulfonyl chloride as the central unit, consecutive desulfitative Heck type reaction followed by palladium-catalysed direct arylation allowed to prepare heteroarylated stilbene derivatives in only two steps.
Pincer complex-catalyzed redox coupling of alkenes with lodonium salts via presumed palladium(IV) itermediates
Aydin, Juhanes,Larsson, Johanna M.,Selander, Nicklas,Szabo, Kalman J.
supporting information; experimental part, p. 2852 - 2854 (2009/12/05)
Palladium pincer complexes directly catalyze the redox coupling reactions of functionalized alkenes and iodonium salts. The catalytic process, which Is suitable for mild catalytic functionalization of allylic acetates and electron-rich alkenes, probably o
SULFURIC ACID ESTERS OF SUGAR ALCOHOLS
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, (2008/06/13)
The present invention is concerned with novel sulfuric acid esters of sugar alcohols and sugar alcohol-like compounds of the formula STR1 Also described are methods for the treatment and/or prophylaxis of arteriosclerotic changes in the vascular wall as well as a process for the manufacture of the compounds of formula I and their salts.