1071508-40-1

Basic information

• Product Name: (CH₃(CH₂)3)3SnCH(C₆H₅)CH₃COO
• CAS NO: 1071508-40-1
• Molecular Weight: 439.226
• Mol File: 1071508-40-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (CH₃(CH₂)3)3SnCH(C₆H₅)CH₃COO(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃(CH₂)3)3SnCH(C₆H₅)CH₃COO(1071508-40-1)
• EPA Substance Registry System: (CH₃(CH₂)3)3SnCH(C₆H₅)CH₃COO(1071508-40-1)

Safety Data

• Hazardous Substances Data: 1071508-40-1(Hazardous Substances Data)

Upstream product

• 155910-42-2 Bu₃SNCH(OH)Ph 
• 108-24-7 acetic anhydride 
• 688-73-3 tri-n-butyl-tin hydride 
• 100-52-7 benzaldehyde 
• 557-20-0 diethylzinc 
• 75-36-5 acetyl chloride 

Downstream Products

• 56894-87-2 4-acetoxy-4-phenyl-butan-2-one 
• 954-67-6 benzhydryl acetate 
• 132587-07-6 1-phenylbut-3-enyl acetate 
• 82027-42-7 Acetic acid ethylsulfanylcarbonyl-phenyl-methyl ester 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 29071-09-8 2-acetoxy-2-phenylacetic acid 
• 86561-27-5 methyl O-acetylmandalate 
• 79416-45-8 (+)-methyl (S)-α-acetoxyphenylacetate 
• 947-94-4 methyl (R)-(-)-2-acetyloxy-2-phenylacetate 

Relevant articles and documents

Α-hydroxyacid salt

PROBLEM TO BE SOLVED: To provide a novel method for manufacturing a salt of α-hydroxy acid as an intermediate for synthesizing α-hydroxy acid derivatives which promotes carboxylation promptly by the COsupplementation reaction even if the substrate having

Stereospecific palladium/copper cocatalyzed cross-coupling of α-alkoxy- and α-aminostannanes with acyl chlorides

Stille-type cross-coupling between α-alkoxy(amino)stannanes and acyl chlorides affords α-hetero-substituted ketones in moderate to good yields when cocatalyzed by Pd and Cu(I) salts. The reaction is applicable to a wide range of tin compounds, especially those bearing α-electron-withdrawing groups such as benzoyloxy or acetyloxy, although some ethers (e.g., MOM) are also satisfactory. Aromatic acid chlorides give the best yields. Coupling of chiral α-alkoxystannanes, readily available by BINAL-H asymmetric reduction of acylstannanes, proceeds with retention of configuration.