107465-92-9

Basic information

• Product Name: 1-cyano-3-diethylphosphonooxy-2-methyl-1-cyclohexene
• CAS NO: 107465-92-9
• Molecular Weight: 273.269
• Mol File: 107465-92-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-cyano-3-diethylphosphonooxy-2-methyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyano-3-diethylphosphonooxy-2-methyl-1-cyclohexene(107465-92-9)
• EPA Substance Registry System: 1-cyano-3-diethylphosphonooxy-2-methyl-1-cyclohexene(107465-92-9)

Safety Data

• Hazardous Substances Data: 107465-92-9(Hazardous Substances Data)

Upstream product

• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 2942-58-7 diethyl cyanophosphonate 

Downstream Products

• 107465-93-0 1-cyano-3-hydroxy-2-methyl-1-cyclohexene 
• 65456-66-8 3-cyano-2-methyl-2-cyclohexen-1-one 

Relevant articles and documents

ALLYLIC REARRANGEMENT OF CYANOPHOSPHATE. II. SYNTHESIS OF β-CYANO-α,β-UNSATURATED KETONES

Boron trifluoride-catalyzed allylic rearrangement of the cyanophosphates of α,β-unsaturated ketones (1a-d, 7 and 14) was found to give the allylic phosphates (3a-d, 9 and 16), which were successfully converted to β-cyano-α,β-unsaturated ketones (6a-d, 13 and 20) by acid hydrolysis (0.5 N HCl) followed by manganese dioxide oxidation of the resulting allylic alcohols(5a-d, 11, 12 and 17).The stereochemical features of the allylic phosphates (9 and 16) are discussed.Keywords-α,β-unsaturated ketone; diethyl phosphorocyanidate; cyanophosphate; allylic rearrangement; boron trifluoride etherate; manganese dioxide; β-cyano-α,β-unsaturated ketone