107750-74-3Relevant articles and documents
An epoxide ring-opening approach for a short and stereoselective synthesis of icetexane diterpenoids
Carita, Adriana,Burtoloso, Antonio C.B.
scheme or table, p. 686 - 688 (2010/04/02)
A new approach for the synthesis of the core skeleton of icetexane diterpenoids is presented and deals with an epoxide ring-opening reaction by metallated aromatic compounds. Employing this strategy, a short synthesis of an icetexane analogue of brussonol was achieved in just four steps from 2-allyl-cyclohexanone.
The C-ring problem of sterol biosynthesis: TiCl4-induced rearrangement into the anti-markovnikov cation corresponding to the C-ring
Nishizawa, Mugio,Iwamoto, Yoshihiro,Takao, Hiroko,Imagawa, Hiroshi,Sugihara, Takumichi
, p. 1685 - 1687 (2007/10/03)
(matrix presented) Cation 9, generated by the reaction of diol 8 and BF3·Et2O, SnCl4, Sc(OTf)3, FeCl3, TiF4, or CF3SO3H, leads to a hydride shift, providing cation 11,
A FACILE ENTRY TO BICYCLIC γ-LACTONES AND A SHORT SYNTHESIS OF (+/-)-DIHYDROACTINIDIOLIDE
Chakraborty, T.K.,Chandrasekaran, S.
, p. 2895 - 2896 (2007/10/02)
A highly useful mode of access to bicyclic γ-lactones 3 from tert-hydroxyolefins 2 with chromium(V) reagent or PCC and its application to the synthesis of (+/-)-dihydroactinidiolide are described.
