109139-28-8

Basic information

• Product Name: N-trifluoromethylsulfonyl-S-amino-S-p-chlorophenylsulfoximide
• Synonyms: N-trifluoromethylsulfonyl-S-amino-S-p-chlorophenylsulfoximide
• CAS NO: 109139-28-8
• Molecular Weight: 322.716
• Mol File: 109139-28-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-trifluoromethylsulfonyl-S-amino-S-p-chlorophenylsulfoximide(CAS DataBase Reference)
• NIST Chemistry Reference: N-trifluoromethylsulfonyl-S-amino-S-p-chlorophenylsulfoximide(109139-28-8)
• EPA Substance Registry System: N-trifluoromethylsulfonyl-S-amino-S-p-chlorophenylsulfoximide(109139-28-8)

Safety Data

• Hazardous Substances Data: 109139-28-8(Hazardous Substances Data)

Upstream product

• 144921-29-9 4-chloro-N-(trifluoromethysulfonyl)benzenesulfonimidoyl fluoride 
• 95414-69-0 S-((p-chloro)phenyl)-S-(trifluoromethyl)-sulfoximine 
• 143921-28-2 C₇H₄Cl₂F₃NO₃S₂ 
• 109139-21-1 C₈H₄ClF₆NO₃S₂ 

Downstream Products

• 98-64-6 4-Chlorobenzenesulfonamide 
• 421-85-2 Trifluoromethanesulfonamide 

Relevant articles and documents

The unusual reactivity of the mono- and bis- N-(trifluoromethylsulfonyl)-substituted azaanalogs of arenesulfonochlorides

The reactions of N-(trifluoromethylsulfonyl)arenesulfonimidoyl- and N,N′-bis (trifluoromethylsulfonyl)arenesulfonodiimidoyl chlorides of general formulas Ar - S(O) (=NSO2CF3)Cl (1) and Ar - S(=NSO2CF3)2Cl (2) with ammonia have been investigated and found to yield the ammonium salts of [N-(trifluoromethylsulfonyl)arenesulfinyliminol-N′- (trifluoromethylsulfonyl)amides. The high oxidative ability of the chlorides (1,2) have been shown. Thus, chlorides (2) react with benzene or trifluoromethylbenzene, to form the chlorobenzene or 3-chloro-trifluoromethylbenzene. The fluorides of the general formulas Ar - S(O) (=NSO2CF3)F and Ar - S(=NSO2CF3)2F have been prepared. Their interaction with ammonia leads to the usual formation of corresponding amides. The electron nature of new electron withdrawing substituents have been investigated.