1096155-69-9

Basic information

• Product Name: (C₆H₄C₆H₄NHCH₂C₆H₅)2Pd₃(CH₃CO₂)4
• CAS NO: 1096155-69-9
• Molecular Weight: 1072.12
• Mol File: 1096155-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₄C₆H₄NHCH₂C₆H₅)2Pd₃(CH₃CO₂)4(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₄C₆H₄NHCH₂C₆H₅)2Pd₃(CH₃CO₂)4(1096155-69-9)
• EPA Substance Registry System: (C₆H₄C₆H₄NHCH₂C₆H₅)2Pd₃(CH₃CO₂)4(1096155-69-9)

Safety Data

• Hazardous Substances Data: 1096155-69-9(Hazardous Substances Data)

Upstream product

• 52648-48-3 N-(phenylmethyl)-(1,1'-biphenyl)-2-amine 
• 3375-31-3 palladium diacetate 

Relevant articles and documents

Oxidative Pd(II)-catalyzed C-H bond amination to carbazole at ambient temperature

We report a new Pd(II)-catalyzed C-H bond amination reaction to form carbazoles, an important motif that is prevalent in a range of systems. The catalytic amination process operates under extremely mild conditions and produces carbazole products in good to excellent yields. Carbazoles possessing complex molecular architecture can also be formed using this reaction, highlighting its potential in natural product synthesis applications. Preliminary mechanistic investigations reveal the reaction proceeds through a Pd(II)/Pd(IV) manifold and that reductive elimination from a high oxidation state Pd(IV) complex facilitates the mild conditions of this transformation. Copyright