1109226-31-4Relevant articles and documents
Palladium-catalysed direct arylations of heteroaromatics using more eco-compatible solvents pentan-1-ol or 3-methylbutan-1-ol
Bensaid, Souhila,Laidaoui, Nouria,El Abed, Douniazad,Kacimi, Soufi,Doucet, Henri
experimental part, p. 1383 - 1387 (2011/03/22)
The palladium-catalysed direct coupling of aryl halides with heteroaromatics in greener solvents than DMF or DMAc, which are often employed for such couplings, would be a considerable advantage for both industrial application and sustainable development.
Ligand-free palladium-catalyzed direct arylation of thiazoles at low catalyst loadings
Roger, Julien,Pozgan, Franc,Doucet, Henri
supporting information; experimental part, p. 1179 - 1186 (2009/08/08)
Ligand-free Pd(OAc)2 was found to catalyze very efficiently the direct arylation of thiazole derivatives under very low catalyst concentration. By using activated aryl bromides, the reaction can be performed employing as little as 0.1-0.001 mol