111294-68-9Relevant articles and documents
Pd-NHC catalyzed conjugate addition versus the mizoroki-heck reaction
Gottumukkala, Aditya L.,Devries, Johannes G.,Minnaard, Adriaan J.
supporting information; experimental part, p. 3091 - 3095 (2011/04/22)
Ace of base: A catalytic system is presented that, solely by choice of the base, selectively switches between conjugate addition and the Mizoroki-Heck reaction of aryl halides with Michael acceptors (see scheme; R, R′=alkyl, aryl). For conjugate addition reactions, this avoids the preparation and use of organometallics.