1115239-87-6

Basic information

• Product Name: [(1,8-naphthyridine)Cu(I)(bis[2-(diphenylphosphino)phenyl]ether)]PF₆
• CAS NO: 1115239-87-6
• Molecular Weight: 877.224
• Mol File: 1115239-87-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1,8-naphthyridine)Cu(I)(bis[2-(diphenylphosphino)phenyl]ether)]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [(1,8-naphthyridine)Cu(I)(bis[2-(diphenylphosphino)phenyl]ether)]PF₆(1115239-87-6)
• EPA Substance Registry System: [(1,8-naphthyridine)Cu(I)(bis[2-(diphenylphosphino)phenyl]ether)]PF₆(1115239-87-6)

Safety Data

• Hazardous Substances Data: 1115239-87-6(Hazardous Substances Data)

Upstream product

• 254-60-4 1,8-naphthyridine 
• 64443-05-6 tetrakis(actonitrile)copper(I) hexafluorophosphate 
• 166330-10-5 bis[2-(diphenylphosphino)phenyl] ether 

Relevant articles and documents

Synthesis, crystal structures, and electronic spectra of (1,8-naphthyridine)ReI(CO)3Cl and [(1,8-naphthyridine)CuI(DPEPhos)]PF6

Two 1,8-naphthyridine (nap) metal complexes (nap)ReI(CO)3Cl (1) and [(nap)CuI(DPEPhos)]PF6 (2) were synthesized and characterized by NMR-, emission, and absorption spectroscopy, elemental analysis, mass spectrometry, and X-ray structural analysis. In both complexes, the nap ligand coordinates with both N atoms to the metal centre in a bidentate manner. 1 and 2 exhibit a broad phosphorescence in solid state at T = 300 K, which is completely quenched in solution at r.t. In addition, the gas-phase structures of both complexes were optimized at the B3LYP/6-31G(d,p) level of theory.