112043-37-5

Basic information

• Product Name: 2,5-Cyclohexadiene-1-carboxylic acid, 1-[3-(2-furanyl)propyl]-2-methoxy-, methyl ester
• CAS NO: 112043-37-5
• Molecular Formula: C16H20O4
• Molecular Weight: 276.332
• Mol File: 112043-37-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadiene-1-carboxylic acid, 1-[3-(2-furanyl)propyl]-2-methoxy-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadiene-1-carboxylic acid, 1-[3-(2-furanyl)propyl]-2-methoxy-, methyl ester(112043-37-5)
• EPA Substance Registry System: 2,5-Cyclohexadiene-1-carboxylic acid, 1-[3-(2-furanyl)propyl]-2-methoxy-, methyl ester(112043-37-5)

Safety Data

• Hazardous Substances Data: 112043-37-5(Hazardous Substances Data)

Upstream product

• 112043-57-9 2-(3-iodopropyl)furan 
• 606-45-1 2-methoxybenzoic acid methyl ester 

Downstream Products

• 112043-43-3 6-(acetoxymethyl)-6-<3-(2-furyl)propyl>-1-methoxy-1,4-cyclohexadiene 
• 112043-38-6 4-<3'-(2-furyl)propyl>-3-methoxy-4-(methoxycarbonyl)cyclohexa-2,5-dien-1-one 
• 112043-42-2 6-<3-(2-furyl)propyl>-6-(hydroxymethyl)-1-methoxy-1,4-cyclohexadiene 

Relevant articles and documents

Intramolecular Cycloadditions to Oxyallyl Zwitterions Generated from Photorearrangements of 2,5-Cyclohexadien-1-ones

Photorearrangement of 2,5-cyclohexadien-1-one 9a gave phenols 12 and 13, while 9b gave bicyclohexenone 10b.No evidence for the formation of an azide-zwitterion cycloadduct was obtained from these examples.However, the 3,6-dimethoxy analogue 9c provided the bridged triazene 14, for which X-ray crystallographic studies confirmed structural assignments for 14 and previously obtained triazenes 5a and 5b. 4--3-methoxy-4-(nethoxycarbonyl)cyclohexa-2,5-dien-1-one (17) photorearranged to bicyclohexenone 18 and phenol 19.The 4-acetoxymethyl derivatives 20a and 20b gave the bridged furan adducts 23a, and 23b in excellent yield.Acetoxymethyl-substituted triazene 27 was obtained from 26c; 27 slowly gave alcohol 28 on exposure to the atmosphere.