1125824-45-4Relevant articles and documents
Elucidating absolute configuration of unsaturated alcohols via enantioselective acylation reactions
Legay, Christina M.,Boudreau, Colton G.,Derksen, Darren J.
, p. 3432 - 3435 (2013/06/26)
Enantioselective nucleophilic acylation catalysis provides a simple method of determining absolute configuration for unsaturated alcohols. Extension of this technique to natural products and synthetic compounds, as well as current limitations of this appr
Indirect trapping of the retroconjugate addition reaction intermediate involved in the epimerization of lobeline: Application to the synthesis of (-)-sedamine
Zheng, Guangrong,Dwoskin, Linda P.,Crooks, Peter A.
, p. 8514 - 8517 (2007/10/03)
Alkyl chloroformates induced indirect trapping of the retroconjugate addition reaction intermediate involved in the epimerization of lobeline is described. This strategy was applied to the conversion of (-)-lobeline to (-)-sedamine in high overall yield.