1132662-27-1

Basic information

• Product Name: benzyl (2R,3R,4S,5R,6R,7R)-7-tert-butyldimethylsilyloxy-3-hydroxy-5,6-O-isopropylidene-2,4,6-trimethylnonanoate
• CAS NO: 1132662-27-1
• Molecular Weight: 508.771
• Mol File: 1132662-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl (2R,3R,4S,5R,6R,7R)-7-tert-butyldimethylsilyloxy-3-hydroxy-5,6-O-isopropylidene-2,4,6-trimethylnonanoate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl (2R,3R,4S,5R,6R,7R)-7-tert-butyldimethylsilyloxy-3-hydroxy-5,6-O-isopropylidene-2,4,6-trimethylnonanoate(1132662-27-1)
• EPA Substance Registry System: benzyl (2R,3R,4S,5R,6R,7R)-7-tert-butyldimethylsilyloxy-3-hydroxy-5,6-O-isopropylidene-2,4,6-trimethylnonanoate(1132662-27-1)

Safety Data

• Hazardous Substances Data: 1132662-27-1(Hazardous Substances Data)

Upstream product

• 122-63-4 benzyl proprionate 

Relevant articles and documents

Efficient syntheses of 13C-labelled erythromycin biosynthetic intermediates. 2: (2S,3S,4S,5R,6R,7R)-3,6,7-trihydroxy-2,4,6-trimethyl[1- 13C]nonan-5-olide and S-2-acetylaminoethyl (2R,3S,4S,5R,6S,7R)-3,5,6, 7-tetrahydroxy-2,4,6-trimethyl [1-13C]nonanethioate

The 13C-labelled putative erythromycin biosynthetic intermediates, ((2S,3S,4S,5R,6R,7R)-3,6,7-trihydroxy-2,4,6-trimethyl[1- 13C]nonan-5-olide and S-2-acetylaminoethyl (2R,3S,4S,5R,6S,7R)-3,5,6, 7-tetrahydroxy-2,4,6-trimethyl[1-13C]nonanethioate), which would be useful for the investigation of the chain elongation mechanism in erythromycin biosynthesis, were efficiently synthesized via aldol condensation of aldehyde derived from (2S,3R,4R,5R)-tert-butyldimethylsilyloxy-5-3,4-O-isopropylidene-2, 4-dimethylheptanol, which was obtained in our previous work on erythromycin A synthesis, and sodium [1-13C]propionate (after conversion to ester). Copyright