1141884-95-8

Basic information

• Product Name: (R)-4-[(Z)-benzylidene]-2-octyloxytetrahydrofuran
• Synonyms: (R)-4-[(Z)-benzylidene]-2-octyloxytetrahydrofuran
• CAS NO: 1141884-95-8
• Molecular Weight: 288.43
• Mol File: 1141884-95-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-[(Z)-benzylidene]-2-octyloxytetrahydrofuran(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-[(Z)-benzylidene]-2-octyloxytetrahydrofuran(1141884-95-8)
• EPA Substance Registry System: (R)-4-[(Z)-benzylidene]-2-octyloxytetrahydrofuran(1141884-95-8)

Safety Data

• Hazardous Substances Data: 1141884-95-8(Hazardous Substances Data)

Upstream product

• 929-62-4 n-octyl vinyl ether 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Relevant articles and documents

Palladium(II)-catalyzed asymmetric coupling of allylic alcohols and vinyl ethers: Insight into the palladium and copper bimetallic catalyst

The use of PdX2, CuX2 (X = OAc, OCOCF3, or Cl), and catechol together with (S,S)-4,4'-bisbenzyl- 2,2'-bioxazoline under O2 induces the asymmetric coupling of cinnamyl alcohols and vinyl ethers to give (R)-(+)-2-alkoxy-4-benzylidenetetrahydrofurans in 40-53% ee (79% yield). The present study provides implications for the so-called Wacker catalyst of PdX2 and CuX2, in terms of that the anionic ligands (X) of Pd and Cu interchange between two metals.