114317-08-7Relevant articles and documents
Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation
Sun, Qi,Meng, Xiangju,Xiao, Feng-Shou,Liu, Xiao,Zhang, Xiaoming,Yang, Yan,Yang, Qihua
, p. 10505 - 10507,3 (2012)
We report here a successful preparation of a heterogeneous chiral catalyst from copolymerization of mesoporous cross-linked polymer with chiral BINAP ligands, followed by coordination of the BINAP with a ruthenium species, which exhibits high activity, excellent enantioselectivity, and extraordinary recyclability in asymmetric hydrogenation.