1146-48-1

Basic information

• Product Name: benzenethiosulfonic acid S-(4-methoxyphenyl) ester
• Synonyms: benzenethiosulfonic acid S-(4-methoxyphenyl) ester
• CAS NO: 1146-48-1
• Molecular Weight: 280.368
• Mol File: 1146-48-1.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: benzenethiosulfonic acid S-(4-methoxyphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: benzenethiosulfonic acid S-(4-methoxyphenyl) ester(1146-48-1)
• EPA Substance Registry System: benzenethiosulfonic acid S-(4-methoxyphenyl) ester(1146-48-1)

Safety Data

• Hazardous Substances Data: 1146-48-1(Hazardous Substances Data)

Upstream product

• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 873-55-2 sodium benzenesulfonate 
• 696-63-9 4-Methoxybenzenethiol 
• 66003-76-7 Diphenyliodonium triflate 
• 95914-29-7 1-(4-methoxyphenyl)-2-phenyldisulfane 
• 6462-50-6 sodium 4-methoxybenzenesulfinate 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 882-33-7 diphenyldisulfane 
• 532-32-1 sodium benzoate 
• 618-41-7 Benzenesulfinic acid 
• 80-17-1 benzenesufonyl hydrazide 
• 84452-54-0 N-4-methoxyphenylthio-1,4-benzoquonone imine 
• 1950-65-8 4-methoxybenzenesulfenyl chloride 

Downstream Products

• 1353898-78-8 4-{[(4-methoxyphenyl)thio]ethynyl}benzonitrile 
• 1353898-77-7 1-bromo-2-{[(4-methoxyphenyl)thio]ethynyl}benzene 
• 1353898-96-0 1-bromo-2-{(E)-2-iodo-1-(4-methoxyphenyl)-2-[(4-methoxyphenyl)thio]vinyl}benzene 
• 1353899-05-4 1-bromo-2-{(1Z)-1-(4-methoxyphenyl)-2-[(4-methoxyphenyl)thio]penta-1,4-dienyl}benzene 
• 1353899-07-6 ethyl 3-{(1E)-1-(4-cyanophenyl)-2-[(4-methoxyphenyl)thio]penta-1,4-dienyl}benzoate 
• 1353899-12-3 ethyl (4E)-5-(4-cyanophenyl)-5-(4-methoxyphenyl)-4-[(4-methoxyphenyl)thio]-2-methylenepent-4-enoate 
• 111698-34-1 (+/-)_S-isopropyl phenylsulfinate 
• 83180-92-1 1-(4-methylphenyldisulfanyl)-4-methoxybenzene 

Relevant articles and documents

Visible-Light-Induced Cyclization/Aromatization of 2-Vinyloxy Arylalkynes: Synthesis of Thio-Substituted Dibenzofuran Derivatives

A visible-light-induced cascade reaction of 2-vinyloxy arylalkynes with thiosulfonates was developed and provided unexpected thio-substituted dibenzofuran derivatives in moderate yields. Mechanistic studies revealed the thiosulfonylation product of 2-vinyloxy arylalkyne was the key intermediate, and the additive disulfide played the role of hydrogen abstraction in the aromatization process to offer the desired product. This reaction presents a new reaction mode for the construction of polycyclic oxygen heterocycles.

Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides

A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates starting from thiosulfonates andN-substituted formamides is developed. By employing rhodamine B as a photocatalyst andtert-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.

Metal-Free Radical Annulation of Oxygen-Containing 1,7-Enynes: Configuration-Selective Synthesis of (E)-3-((Arylsulfonyl)methyl)-4-Substituted Arylidenechromene Derivatives

A novel strategy for the synthesis of (E)-3-((arylsulfonyl)methyl)-4-substituted benzylidenechromene derivatives via a metal-free radical annulation reaction of oxygen-containing 1,7-enynes with thiosulfonates has been developed. The reaction shows broad substrate scope, wide functional group tolerance, and moderate to excellent yields. Moreover, thiosulfonates were well driven to achieve the bifunctionalization reaction of oxo-1,7-enynes which derived from aliphatic alkynes. In addition, the (E)-configuration of the products was highly controlled by the structure of 1,7-enyne.