114953-61-6

Basic information

• Product Name: 1,2-dichloro-1,2,2-trifluoroethyl phenyl selenide
• Synonyms: 1,2-dichloro-1,2,2-trifluoroethyl phenyl selenide
• CAS NO: 114953-61-6
• Molecular Weight: 307.989
• Mol File: 114953-61-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,2-dichloro-1,2,2-trifluoroethyl phenyl selenide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-dichloro-1,2,2-trifluoroethyl phenyl selenide(114953-61-6)
• EPA Substance Registry System: 1,2-dichloro-1,2,2-trifluoroethyl phenyl selenide(114953-61-6)

Safety Data

• Hazardous Substances Data: 114953-61-6(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 79-38-9 Chlorotrifluoroethylene 

Downstream Products

• 1666-13-3 diphenyl diselenide 
• 114953-78-5 E-1,2-difluoro-2-chlorovinyl phenyl selenide 
• 102688-05-1 1,2,2-trifluorovinyl phenyl selenide 

Relevant articles and documents

SYNTHESIS OF FLUORINATED VINYL SULFIDES AND SELENIDES

The reaction between fluoroolefins 1 and 10e and benzenesulfenyl or selenenyl halides 6 is found to be solvent-dependent and gives in most cases predominantly the regioisomer 8.The structure of adducts 8 and 9 are ascertained by 1H, 19F and 77Se NMR spectroscopy.Compounds 8 are easily halogenated and treatment of the products with magnesium or zinc leads to the desired polyfluorovinyl sulfides and selenides 10.A second route of synthesis of these reagents results from the reaction of fluorovinyllithio-derivatives 11 with benzenesulfenyl or selenenyl halides.Olefin 10e is also obtained from the selenoacetal 8t of trifluoroacetaldehyde.