1154062-17-5

Basic information

• Product Name: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester
• Synonyms: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester
• CAS NO: 1154062-17-5
• Molecular Weight: 450.575
• Mol File: 1154062-17-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester(1154062-17-5)
• EPA Substance Registry System: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester(1154062-17-5)

Safety Data

• Hazardous Substances Data: 1154062-17-5(Hazardous Substances Data)

Upstream product

• 1154062-14-2 propenoic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 120-74-1 (1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 

Relevant articles and documents

Chiral linker 5: scope and limitations of arylsubstituted m-hydrobenzoins as solid supported open chain chiral auxiliaries for diastereoselective syntheses

The applicability of five aryl substituted m-hydrobenzoin ethers already tested in the L-Selectride mediated stereoselective reduction of phenylglyoxylates as open chain chiral auxiliaries was further investigated via the α-alkylation of propionates, the addition of n-BuZnCl to phenylglyoxylates and the Diels-Alder reaction of acrylates with cyclopentadiene as model reactions. As up to 90% de could be achieved in the solution phase, two optimized auxiliary structures were immobilized on commercially available Wang-resin and applied as a reusable solid supported chiral auxiliaries in the same type of reactions.