115422-51-0

Basic information

• Product Name: 1,4-bis[bis(4-methoxyphenyl)hydroxymethyl]benzene
• Synonyms: 1,4-bis[bis(4-methoxyphenyl)hydroxymethyl]benzene
• CAS NO: 115422-51-0
• Molecular Weight: 562.662
• Mol File: 115422-51-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,4-bis[bis(4-methoxyphenyl)hydroxymethyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-bis[bis(4-methoxyphenyl)hydroxymethyl]benzene(115422-51-0)
• EPA Substance Registry System: 1,4-bis[bis(4-methoxyphenyl)hydroxymethyl]benzene(115422-51-0)

Safety Data

• Hazardous Substances Data: 115422-51-0(Hazardous Substances Data)

Upstream product

• 120-61-6 1,4-benzenedicarboxylic acid dimethyl ester 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 103509-96-2 1,4-bis-(4,α,4'-trimethoxy-benzhydryl)-benzene 
• 18066-45-0 1,4-Bisbenzol 
• 1063745-81-2 1,4-bis[bis(4-methoxyphenyl)-4-hydroxyphenylmethyl]benzene 
• 1063745-85-6 1,4-phenylenebis(tri(4'-hydroxyphenyl)methane) 
• 140149-16-2 1,4-Bismethyl>benzol 

Relevant articles and documents

Synthesis and topological determination of hexakis-substituted 1,4-ditritylbenzene and nonakis-substituted 1,3,5-tritritylbenzene derivatives: Building blocks for higher supramolecular assemblies

Based on trityl moieties, novel organic building blocks have been prepared and structurally investigated. Substituted hexaphenyl-p-xylene (1,4-ditritylbenzene) as well as extended analogues thereof were prepared. Furthermore, a new family based on a 1,3,5-tritritylbenzene motif, connecting three trityl groups through a formal mesitylene unit, was developed. Both families were further converted through six-and nine-fold substitution reactions, respectively, to yield potent molecular building blocks for supramolecular assemblies.

Nanostructured columnar and cubic liquid-crystalline assemblies consisting of unconventional rigid mesogens based on triphenylmethanes

Liquid-crystalline (LC) molecules of unconventional shapes that form columnar and micellar cubic structures have been synthesized using triarylmethyl moieties as building blocks. The molecules have bowl- and dumbbell-shape. Despite the rigidity and bulkiness of the triarylmethyl moieties, the molecules form columnar and micellar cubic LC phases. The bowl-shaped molecules containing one triarylmethyl moiety show LC phases. The LC temperature ranges of the dumbbell-shaped molecules containing two triarylmethyl moieties connected by rigid rods are wider than those of bowl-shaped molecules containing one triarylmethyl moiety. The UV-vis spectroscopy of the dumbbell-shaped molecules having a terphenyl moiety reveals that the terphenyl moieties aggregate in the mesophase.