116118-00-4

Basic information

• Product Name: 1-phenyl-1-methoxy-2-phenylselenenyl propane dichloride, erythro
• Synonyms: 1-phenyl-1-methoxy-2-phenylselenenyl propane dichloride, erythro
• CAS NO: 116118-00-4
• Molecular Weight: 376.184
• Mol File: 116118-00-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenyl-1-methoxy-2-phenylselenenyl propane dichloride, erythro(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-1-methoxy-2-phenylselenenyl propane dichloride, erythro(116118-00-4)
• EPA Substance Registry System: 1-phenyl-1-methoxy-2-phenylselenenyl propane dichloride, erythro(116118-00-4)

Safety Data

• Hazardous Substances Data: 116118-00-4(Hazardous Substances Data)

Upstream product

• 873-66-5 1-propenylbenzene 
• 5707-04-0 Phenylselenyl chloride 
• 74880-71-0 1-phenyl-1-methoxy-2-phenylselenenyl propane 

Downstream Products

• 22665-13-0 1-phenylallyl methyl ether 
• 90-87-9 2-phenylpropionaldehyde dimethyl acetal 
• 36391-93-2 1-phenyl-1,2-dimethoxy propane, erythro 
• 36391-93-2 1-phenyl-1,2-dimethoxy propane, threo 

Relevant articles and documents

METHOXYCHLORINATION AND DIMETHOXYLATION OF ALKENES. THE REACTIONS OF SUBSTITUTED STYRENES WITH PHENYLSELENENYL CHLORIDE IN METHANOL

The addition of PhSeCl to α- and β-substituted styrenes in methanol is regio- and stereospecific and affords the products of methoxyselenenylation.These compounds further react with PhSeCl to give the deselenenylation products.In the case of α-substituted styrenes, 1-methoxy, 2-chloroalkanes are produced, whereas with β-substituted styrenes the major reaction products are the 1,2-dimethoxyalkanes and the 2,2-dimethoxyalkanes in which phenyl migration has occured.It is shown that these reactions proceed through the intermediate formation of the alkyl phenylselenium dichlorides, PhCR(OMe)CHR1SeCl2Ph, which evolve with different mechanisms depending on the structure of the starting alkenes.