116974-88-0

Basic information

• Product Name: diacetyl-formyl-amine
• Synonyms: diacetyl-formyl-amine
• CAS NO: 116974-88-0
• Molecular Weight: 129.115
• Mol File: 116974-88-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diacetyl-formyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: diacetyl-formyl-amine(116974-88-0)
• EPA Substance Registry System: diacetyl-formyl-amine(116974-88-0)

Safety Data

• Hazardous Substances Data: 116974-88-0(Hazardous Substances Data)

Upstream product

• 117049-21-5 (1S,4R)-4,6-Dimethyl-2,3,7-trioxa-5-aza-bicyclo[2.2.1]hept-5-ene 
• 117049-22-6 (1R,4S)-1,4-Dimethyl-2,3,7-trioxa-5-aza-bicyclo[2.2.1]hept-5-ene 

Relevant articles and documents

THERMAL TRANSFORMATIONS OF OXAZOLE ENDOPEROXIDES: REARRANGEMENTS, FRAGMENTATIONS AND METHANOL ADDITIONS

Oxazole endoperoxides 1 carrying a phenyl group at C-2 rearrange to triacylamines 3; those carrying a hydrogen atom at C-2 undergo a fragmentation into 1:1 mixtures of nitriles (or HCN) 4 and anhydrides 5, whereas methyl substitution at C-2 gives rise to competition between these two modes of reaction.Methanol addition to 1 leads to 4-methoxy-5-hydroperoxides 6 which easily transform into methyl esters 7 and diacylamines 8.