117226-60-5Relevant articles and documents
Reactions of Germylenes with Azides: Iminogermanes, Azidogermanes, Tetrazagermoles, and Hexaazadigermadispirododecanes
Pfeiffer, Joachim,Maringgele, Walter,Noltemeyer, Mathias,Meller, Anton
, p. 245 - 252 (2007/10/02)
Germylenes; X2Ge, stabilized by steric blocking and/or incorporation into five-membered ring systems, react with azido compounds YN3 depending on the steric requirements of the substituents X and Y to give iminogermanes X2Ge=NY (1,2) azidogermanes X2Ge(N3)NY2 (6-8) tetrazagermoles, X2Ge(-NY-N=)2 (10-16), and hexaazadigermadispirododecanes, 2 (17,18).NMR (1H, 13C, 14N, 15N, and 29Si), MS data, and X-ray structure analyses of the compounds 8, 9, 16, and 18 are reported. - Keywords: Germylenes/ Germanium nitrogen compounds