118739-67-6

Basic information

• Product Name: (1S,5S)-5-Phenyl-6-vinyl-bicyclo[3.2.0]heptan-6-ol
• Synonyms: (1S,5S)-5-Phenyl-6-vinyl-bicyclo[3.2.0]heptan-6-ol
• CAS NO: 118739-67-6
• Molecular Weight: 214.307
• Mol File: 118739-67-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,5S)-5-Phenyl-6-vinyl-bicyclo[3.2.0]heptan-6-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5S)-5-Phenyl-6-vinyl-bicyclo[3.2.0]heptan-6-ol(118739-67-6)
• EPA Substance Registry System: (1S,5S)-5-Phenyl-6-vinyl-bicyclo[3.2.0]heptan-6-ol(118739-67-6)

Safety Data

• Hazardous Substances Data: 118739-67-6(Hazardous Substances Data)

Upstream product

• 1119-51-3 bromopentene 
• 115420-26-3 2-phenyl-6-heptenoic acid 
• 118739-56-3 2-Phenyl-hept-6-enoyl chloride 
• 103-82-2 phenylacetic acid 
• 917-57-7 vinyllithium 
• 29820-45-9 (1S,5S)-5-Phenyl-bicyclo[3.2.0]heptan-6-one 

Downstream Products

• 825-54-7 cyclopent-1-en-1-ylbenzene 
• 118739-68-7 (3aS,7aS)-7a-Phenyl-octahydro-inden-5-one 

Relevant articles and documents

INTRAMOLECULAR CYCLOADDITIONS OF ARYLKETENES WITH ALKENES. REACTIONS OF 5-ARYLBICYCLOHEPTAN-6-ONES.

Intramolecular cycloadditions of arylketenes 4 proceed in excellent yield to give 5-arylbicycloheptan-6-ones 5.Reaction of 5a with KOH in THF gives a 95:5 mixture of 7 and 10.Reaction of 5a with KOEt in ETOH give a 1:3 mixture of 7 and 10.Reaction of 5a with vinyllithium and treatment of the resulting alcohol 23 with KH gives the 1,3-sigmatropic rearrangement product 25.