1203350-99-5

Basic information

• Product Name: C₁₇H₁₂ClFN₂O₂
• CAS NO: 1203350-99-5
• Molecular Weight: 330.746
• Mol File: 1203350-99-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₇H₁₂ClFN₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₇H₁₂ClFN₂O₂(1203350-99-5)
• EPA Substance Registry System: C₁₇H₁₂ClFN₂O₂(1203350-99-5)

Safety Data

• Hazardous Substances Data: 1203350-99-5(Hazardous Substances Data)

Upstream product

• 403-43-0 4-fluorobenzoyl chloride 
• 13024-90-3 1-(4-chlorophenyl)-3-methyl-2-pyrazolin-5-one 

Relevant articles and documents

Synthesis and structural characterization of aluminum complexes supported by NNO-tridentate ketiminate ligands: Efficient catalysts for ring-opening polymerization of l-lactide

Four NNO-tridentate ketiminate derivatives (HL-H, FL-H, OMeL-H and tBuL-H) were prepared through the condensation reaction of 1-(4-chlorophenyl)-4-(4-X-benzoyl)-3-methyl-1H- pyrazol-5(4H)-one (X = H, F, OMe, tBu) with N,N-dimethylenediamine (1.1 molar equiv) under reflux condition. Further reaction of AlMe3 (1.2 molar equiv) with HL-H, FL-H, OMeL-H and tBuL-H, respectively, affords penta-coordinated mono-adduct aluminum complexes [(HL)AlMe2] (1), [(FL)AlMe 2] (2), [(OMeL)AlMe2] (3), and [( tBuL)AlMe2] (4) in high yield. Experimental results indicate complexes 1-4 are active catalysts for ring-opening polymerization of l-lactide (l-LA) in the presence of benzyl alcohol (BnOH). Al complex 2 catalyzes efficiently not only in a "living" fashion but also an "immortal" manner, giving polymers with the expected molecular weights and narrow PDIs.