121077-51-8Relevant articles and documents
Palladium-catalysed atom-economical synthesis of conjugated dienals from terminal acetylenes and acrolein
Hearne, Zo?,Li, Chao-Jun
, p. 6136 - 6139 (2017/07/10)
Conjugated (E,E)-dienals are versatile synthetic intermediates owing to their trifunctional, electrophilic nature and the prevalence of the (E,E)-diene in a wide range of functional molecules. It is shown herein that (E,E)-dienals can be readily prepared
The use of pyrylium tetrafluoroborate for the stereoselective synthesis of 2Z,4E-dienals
Belosludtsev,Borer,Taylor
, p. 320 - 322 (2007/10/02)
The addition of organolithium reagents to pyrylium tetrafluoroborate followed by in situ electrocyclic ring opening of the intermediate 2H-pyrans givens the title Z,E-dienals with high stereoselectivity.
Synthesis of polyconjugated aldehydes using a new Horner--Wadsworth--Emmons reagent.
Rein,Akermark,Helquist
, p. 569 - 572 (2007/10/02)
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