122588-55-0

Basic information

• Product Name: methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside
• Synonyms: methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside
• CAS NO: 122588-55-0
• Molecular Weight: 612.838
• Mol File: 122588-55-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside(122588-55-0)
• EPA Substance Registry System: methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside(122588-55-0)

Safety Data

• Hazardous Substances Data: 122588-55-0(Hazardous Substances Data)

Upstream product

• 40653-15-4 methyl 2,3,4-tri-O-benzyl-α-D-manno-hexodialdo-1,5-pyranoside 
• 107735-20-6 [(dimethylphenylsilyl)methyl]magnesium chloride 
• 122588-57-2 methyl-2,3,4,6-tetra-O-benzyl-7-(dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside 
• 34212-64-1 methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 

Downstream Products

• 122588-51-6 methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside 
• 122588-61-8 (2S,3S,4S,5S,6S)-2-[(R)-2-(Dimethyl-phenyl-silanyl)-1-hydroxy-ethyl]-6-methoxy-tetrahydro-pyran-3,4,5-triol 
• 122588-56-1 (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-vinyl-tetrahydro-pyran 
• 122588-59-4 methyl 2,3,4,6-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside 
• 122588-60-7 Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-[(S)-2-hydroxy-1-((2R,3S,4S,5S,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-ethoxy]-tetrahydro-pyran-3-yl ester 
• 122588-62-9 Acetic acid (2S,3R,4S,5S,6S)-4,5-diacetoxy-2-[(R)-1-acetoxy-2-(dimethyl-phenyl-silanyl)-ethyl]-6-methoxy-tetrahydro-pyran-3-yl ester 
• 122588-52-7 (2R,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methoxy-tetrahydro-pyran 
• 122588-58-3 Acetic acid (2S,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-[(R)-2-(dimethyl-phenyl-silanyl)-1-((2S,3S,4S,5S,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-ethoxy]-tetrahydro-pyran-3-yl ester 
• 122588-57-2 methyl-2,3,4,6-tetra-O-benzyl-7-(dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside 

Relevant articles and documents

Multigram-scale synthesis of L,D-heptoside using a Fleming-Tamao oxidation promoted by mercuric trifluoroacetate

An efficient multigram-scale synthesis of methyl 2,3,4,6-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside from methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside is reported. It involves a sequence of Swern oxidation, Grignard addition and Fleming-Tamao reac