123730-15-4

Basic information

• Product Name: 8-(2'-nitrophenyl)-quinoline
• Synonyms: 8-(2'-nitrophenyl)-quinoline
• CAS NO: 123730-15-4
• Molecular Weight: 250.257
• Mol File: 123730-15-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 8-(2'-nitrophenyl)-quinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 8-(2'-nitrophenyl)-quinoline(123730-15-4)
• EPA Substance Registry System: 8-(2'-nitrophenyl)-quinoline(123730-15-4)

Safety Data

• Hazardous Substances Data: 123730-15-4(Hazardous Substances Data)

Upstream product

• 16567-18-3 8-bromoquinoline 
• 86-58-8 8-quinolinylboronic acid 
• 577-19-5 2-nitrophenyl bromide 
• 108530-08-1 quinolin-8-yl trifluoromethanesulfonate 
• 15163-59-4 potassium o-nitrobenzoate 
• 35883-86-4 2-amino-2'-nitrobiphenyl 
• 56-81-5 glycerol 

Relevant articles and documents

COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME

A compound represented by Formula 1 or Formula 2, and an organic light-emitting device including a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer and the compound represented by Formula 1 or Formula 2.

Biaryl and aryl ketone synthesis via Pd-catalyzed decarboxylase coupling of carboxylate salts with aryl triflates

A bimetallic catalyst system has been developed that for the first time allows the decarboxylative crosscoupling of aryl and acyl carboxylates with aryl triflates. In contrast to aryl halides, these electrophiles give rise to non-coordinating anions as byproducts, which do not interfere with the decarboxylation step that leads to the generation of the carbon nucleophilic crosscoupling partner. As a result, the scope of carboxylate substrates usable in this transformation was extended from ortho-substituted or otherwise activated derivatives to a broad range of ortho-, meta-, and para-substituted aromatic carboxylates. Two alternative protocols have been optimized, one involving heating the substrates in the presence of CuI/1,10- phenanthroline (10-15 mol %) and PdI2/phosphine (23 mol%) in NMP for 1-24 h, the other involving CuI/l,10-phenanthroline (615mol%) and PdBr2/Tol-BINAP (2 mol % ) in NMP using microwave heating for 5-10 min. While most products are accessible using standard heating, the use of microwave irradiation was found to be beneficial especially for the conversion of non-activated carboxylates with functionalized aryl triflates. The synthetic utility of the transformation is demonstrated with 48 examples showing the scope and limitations of both protocols. In mechanistic studies, the special role of microwave irradiation is elucidated, and further perspectives of decarboxylase crosscouplings are discussed.

Heterocyclic mesomeric betaines. Part 2. Synthesis of a hetero derivative of the benzo[b]phenalenide anion

Reductive cyclization of 2,4-dimethyl-8-(2-nitrophenyl)quinoline with hot triethyl phosphite afforded 2,4-dimethyl-7H-pyrido[3,2-c]carbazole (10) and 4,6-dimethyl-6aλ5,7-diazabenz[de]anthracen-6a-ium-7-ide (4; R = Me). The latter is the first example of a conjugated heterocyclic mesomeric betaine isoconjugate with the benzo[b]phenalenide anion.