1242097-49-9Relevant articles and documents
Convergent synthesis of trisubstituted Z -allylic esters by wittig-schlosser reaction
Hodgson, David M.,Arif, Tanzeel
supporting information; experimental part, p. 4204 - 4207 (2010/12/24)
β-Lithiooxyphosphonium ylides, generated in situ from aldehydes and Wittig reagents, react readily with halomethyl esters to form trisubstituted Z-allylic esters. The methodology was applied to a total synthesis of the geranylgeraniol-derived diterpene (6S,7R,Z)-7-hydroxy-2-((E)-6-hydroxy-4- methylhex-4-enylidene)-6,10-dimethylundec-9-enyl acetate (12).