124316-00-3 Usage
Description
N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE is a chemical compound that serves as a versatile reagent in various organic synthesis processes. It is characterized by its unique structure, which includes a triphenylphosphoranylidene group attached to a benzotriazole core, with a methanamine substituent. N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE is known for its ability to participate in a range of chemical reactions, making it a valuable tool in the field of organic chemistry.
Uses
Used in Organic Synthesis:
N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE is used as a reactant for Grignard reactions, which are a class of chemical reactions that involve the formation of carbon-carbon bonds. N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE plays a crucial role in facilitating these reactions, leading to the formation of new organic compounds.
Used in the Preparation of N,N-Bis(but-3-enyl)amines:
N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE is used as a reactant in the aza-Wittig reaction with aldehydes, which is followed by a double Grignard reaction with allylmagnesium bromide. This process results in the formation of N,N-Bis(but-3-enyl)amines, which are valuable intermediates in the synthesis of various organic compounds.
Used in the Synthesis of N-alkyliminophosphoranes and a-functionalized N-alkyliminophosphoranes:
N-(TRIPHENYLPHOSPHORANYLIDENE)-1H-BENZOTRIAZOLE-1-METHANAMINE is also utilized in the synthesis of N-alkyliminophosphoranes and their a-functionalized derivatives. These compounds are important in the development of new pharmaceuticals and agrochemicals, as well as in the creation of advanced materials with unique properties.
Check Digit Verification of cas no
The CAS Registry Mumber 124316-00-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,4,3,1 and 6 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 124316-00:
(8*1)+(7*2)+(6*4)+(5*3)+(4*1)+(3*6)+(2*0)+(1*0)=83
83 % 10 = 3
So 124316-00-3 is a valid CAS Registry Number.
InChI:InChI=1/C25H21N4P/c1-4-12-21(13-5-1)30(22-14-6-2-7-15-22,23-16-8-3-9-17-23)26-20-29-25-19-11-10-18-24(25)27-28-29/h1-19H,20H2
124316-00-3Relevant articles and documents
1-(Triphenylphosphorylideneaminomethyl)benzotriazole (BETMIP) a Novel +CH2N= Synthetic Equivalent: Its Application to the Synthesis of Carbodiimides, Imines, Isothiocyanates, Aziridines, and Secondary Amines
Katritzky, Alan R.,Jiang, Jinglong,Urogdi, Laszlo
, p. 565 - 567 (2007/10/02)
One-carbon homologation has been achieved in novel syntheses of the title compounds by one-pot reaction of 1-(triphenylphosphorylideneaminomethyl)benzotriazole (1) with Grignard reagents followed by in situ transformations of the phosphorazene functionality with isocyanates, aldehydes, carbon disulfide, ethylene oxide, and alkyl halides, respectively.
