1245572-22-8

Basic information

• Product Name: C₁₆H₂₄O₂
• CAS NO: 1245572-22-8
• Molecular Weight: 248.365
• Mol File: 1245572-22-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₂₄O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₂₄O₂(1245572-22-8)
• EPA Substance Registry System: C₁₆H₂₄O₂(1245572-22-8)

Safety Data

• Hazardous Substances Data: 1245572-22-8(Hazardous Substances Data)

Upstream product

• 1129-65-3 (hex-1-yn-1-yl)benzene 
• 584-03-2 1,2-dihydroxybutane 

Relevant articles and documents

Regio- And stereoselective intermolecular hydroalkoxylation of alkynes catalysed by cationic gold(I) complexes

Vinyl ethers and ketals are obtained from the reaction of phenylacetylene derivatives and dimethyl acetylenedicarboxylate (DMAD) with alcohols in good yields and levels of stereoselectivity by using cationic gold(I)-phosphine complexes as catalysts. By choosing the appropriate phosphine, the selective formation of the Z or the E isomer of the vinyl ether can be tuned, and the undesired formation of the ketal can be controlled. The isomerisation of fumarates (Z-isomer) to maleates (E-isomer) is a gold-catalysed process that can be conducted in onepot. When using polyols, 5-membered cyclic ketals are easily isolated by extraction with hexane and the gold complex can be reused.