1246013-66-0Relevant articles and documents
Synthesis of aryl fluorides on a solid support and in solution by utilizing a fluorinated solvent
Doebele, Marion,Vanderheiden, Sylvia,Jung, Nicole,Braese, Stefan
, p. 5986 - 5988 (2010)
(Figure Presented) F for fast: The perfluorinated solvent C 6F14 is the key to a new variant of the BalzSchiemann reaction for the synthesis of fluorinated arenes. Triazenes are converted into fluoroarenes under mild con-ditions on a support and in solution (see scheme). The method is straightforward and inexpensive, and yields previously difficult-to-prepare fluoroarenes in high purity.
