1258278-93-1

Basic information

• Product Name: (3-bromonaphthalen-2-yl)(2-bromophenyl)methanol
• Synonyms: (3-bromonaphthalen-2-yl)(2-bromophenyl)methanol
• CAS NO: 1258278-93-1
• Molecular Weight: 392.09
• Mol File: 1258278-93-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3-bromonaphthalen-2-yl)(2-bromophenyl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (3-bromonaphthalen-2-yl)(2-bromophenyl)methanol(1258278-93-1)
• EPA Substance Registry System: (3-bromonaphthalen-2-yl)(2-bromophenyl)methanol(1258278-93-1)

Safety Data

• Hazardous Substances Data: 1258278-93-1(Hazardous Substances Data)

Upstream product

• 106750-88-3 6,7-dibromo-1,4-epoxy-1,4-dihydronaphthalene 
• 636-28-2 1,2,4,5-tetrabromobenzene 
• 13214-70-5 2,3-dibromonaphthalene 
• 6630-33-7 ortho-bromobenzaldehyde 

Downstream Products

• 1258278-94-2 2-bromo-3-(2-bromobenzyl)naphthalene 
• 257-89-6 benz[b]acridine 

Relevant articles and documents

Copper-Catalyzed N,N-Diarylation of Amides for the Construction of 9,10-Dihydroacridine Structure and Applications in the Synthesis of Diverse Nitrogen-Embedded Polyacenes

We reported herein CuI/DMEDA catalyzed N,N-diarylation reaction of amides with various di(o-bromoaryl)methanes to produce diverse 9,10-dihydroacridine derivatives. The resulting 9,10-dihydroacridine derivatives were oxidized selectively under mild conditions to afford acridine, acridinone, and acridinium derivatives. The copper-catalyzed N,N-diarylation reaction coupled with oxidative aromatization reaction enabled the facile construction of nitrogen atom-embedded tetracenes and pentacenes of different ortho-fused patterns. The luminescence properties, especially the effect of fusion pattern on fluorescence emission of acquired N-polycenes, were also demonstrated.

Synthesis and comparative characterization of 9-boraanthracene, 5-boranaphthacene, and 6-borapentacene stabilized by the H2IMes carbene

A general procedure for the preparation of three N-heterocyclic carbene stabilized, boron-containing acenes (9-boraanthracene, 5-boranaphthacene, and 6-borapentacene) is presented. The key steps involve a transmetallation reaction between BCl3 and an appropriate stannacyclic precursor, and the dehydrochlorination of the H2IMes adduct of the chloroborane product. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues. Just add boron: Synthetic routes to the N-heterocyclic-carbene-stabilized 5-boranaphthacene and 6-borapentacene are described and complement that previously developed for 9-boraanthracene. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues.