127567-55-9

Basic information

• Product Name: 4-methylphenyl 1-naphthyl sulfide
• Synonyms: 4-methylphenyl 1-naphthyl sulfide
• CAS NO: 127567-55-9
• Molecular Weight: 250.364
• Mol File: 127567-55-9.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 4-methylphenyl 1-naphthyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methylphenyl 1-naphthyl sulfide(127567-55-9)
• EPA Substance Registry System: 4-methylphenyl 1-naphthyl sulfide(127567-55-9)

Safety Data

• Hazardous Substances Data: 127567-55-9(Hazardous Substances Data)

Upstream product

• 90-15-3 α-naphthol 
• 106-45-6 para-thiocresol 
• 90-11-9 1-Bromonaphthalene 
• 90-14-2 1-Iodonaphthalene 
• 1402551-70-5 [(1,10-phenanthroline)Cu(μ-p-thiocresol(-1H))]2 
• 830-81-9 1-naphthyl acetate 
• 5720-05-8 4-methylphenylboronic acid 
• 68211-49-4 1-naphthyl tosylate 
• 35424-74-9 1-naphthalenecarbonyl fluoride 
• 106-38-7 para-bromotoluene 
• 99747-74-7 1-naphthyl triflate 
• 103-19-5 di(p-tolyl) disulfide 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 83821-53-8 8-methylbenzo[b]naphtho[2,1-d]thiophene 
• 10375-69-6 1-(p-tolylsulfinyl)naphthalene 

Relevant articles and documents

Iodine-Promoted Tunable Synthesis of 2-Naphthyl Thioethers and 1-Naphthyl Thioethers

An iodine-promoted regioselective sulfenylation/deoxygenation/aromatization reaction of 1-tetralones with disulfides has been developed. This process could be modified to synthesize 2-naphthyl thioethers and 1-naphthyl thioethers in moderate to excellent

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

NiFe2O4 as a magnetically recoverable nanocatalyst for odourless C–S bond formation via the cleavage of C–O bond in the presence of S8 under mild and green conditions

We present green methodologies for one-pot and odourless syntheses of unsymmetric and symmetric diaryl sulfides via C─O bond activation using NiFe2O4 magnetic nanoparticles as a reusable heterogeneous nanocatalyst. The synthesis of unsymmetric sulfides is performed using the cross-coupling reaction of phenolic esters such as acetates, triflates and tosylates with arylboronic acid/S8 or triphenyltin chloride/S8 as thiolating agents in the presence of base and NiFe2O4 magnetic nanoparticles as a catalyst in poly(ethylene glycol) as solvent at 60–85°C. Also, the synthesis of symmetric diaryl sulfides from phenolic compounds using S8 as the sulfur source and NiFe2O4 as catalyst in dimethylformamide at 120°C is described. Using these protocols, the syntheses of various unsymmetric and symmetric sulfides become easier than using the available protocols due to the use of a magnetically reusable bimetallic nanocatalyst and avoiding the use of thiols and aryl halides.