128315-94-6

Basic information

• Product Name: 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane
• CAS NO: 128315-94-6
• Molecular Weight: 291.968
• Mol File: 128315-94-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane(128315-94-6)
• EPA Substance Registry System: 3-methoxy-7α-iodomethyl-3-borabicyclo<3.3.1>nonane(128315-94-6)

Safety Data

• Hazardous Substances Data: 128315-94-6(Hazardous Substances Data)

Upstream product

• 61357-36-6 1-boraadamantane tetrahydrofuranate 
• 865-34-9 lithium methanolate 

Downstream Products

• 128315-96-8 7α-hydroxymethyl-3-azabicyclo<3.3.1>nonane 
• 88269-11-8 (3-Hydroxymethyl-5-methoxymethyl-cyclohexyl)-methanol 
• 281-27-6 1-aza-adamantane 

Relevant articles and documents

ORGANOBORON COMPOUNDS. CDIII. IODINATION OF ATE COMPLEXES OF 1-BORAADAMANTANE

The complex of 1-boraadamantane with tetrahydrofuran (1) reacts with iodine in the presence of lithium methylate or methyllithium to produce 3-methoxy- (III) and 3-methyl-7-iodomethyl-3-borabicyclononane (X), respectively.Further iodination of III in the presence of lithium methylate proceeds in a complicated manner due to replacement of iodine by the methoxy group in the starting compound.The high reactivity of the halogen in III permitted a one-pot synthesis of 3-methoxy-7-methoxymethyl-3-borabicyclononane from I.Iodination of lithium 1-isopropenyl-1-boraadamantanate leads, after methanolysis, to 3-methoxy-7-isobutenyl-3-borabicyclononane.The latter compound was converted to 7-isobutenyl-3-methyl-3-borabicyclononane on treatment with MeMgI.