128348-58-3

Basic information

• Product Name: 2,2,2-trichloro-1-(4-chlorophenyl)ethyl methyl ether
• Synonyms: 2,2,2-trichloro-1-(4-chlorophenyl)ethyl methyl ether
• CAS NO: 128348-58-3
• Molecular Weight: 273.974
• Mol File: 128348-58-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloro-1-(4-chlorophenyl)ethyl methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloro-1-(4-chlorophenyl)ethyl methyl ether(128348-58-3)
• EPA Substance Registry System: 2,2,2-trichloro-1-(4-chlorophenyl)ethyl methyl ether(128348-58-3)

Safety Data

• Hazardous Substances Data: 128348-58-3(Hazardous Substances Data)

Upstream product

• 27704-37-6 2,2,2-trichloro-1-(4-chlorophenyl)ethanone 
• 5333-82-4 2,2,2-trichloro-1-(4-chloro-phenyl)-ethanol 
• 74-88-4 methyl iodide 

Downstream Products

• 1020670-82-9 (Z)-2-chloro-1-(4-chlorophenyl)ethenyl methyl ether 

Relevant articles and documents

1,2-H shift in copper-chlorocarbenoid intermediate during CuCl/bpy-promoted stereoselective dechlorination of 2,2,2-trichloroethyl alkyl ethers to (Z)-1-alkoxy-2-chloroethenes

(Chemical Equation Presented) Reaction of 2,2,2-trichloroethyl alkyl ethers with 2 molar equiv of CuCl/bpy in refluxing DCE yielded (Z)-1-alkoxy-2- chloroethenes stereoselectively as the major product via 1,2-H shift in copper-chlorocarbenoid intermediate. 2,2,2-Trichloroethyl carboxylates undergo a radical 1,2-acyloxy shift under similar conditions.